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Preparation and Characterization of Fe-N Co-doped TiO2 and Its Effect on Photocatalytic Oxidation of 2-MIB in Water

Received: 16 November 2017     Published: 21 November 2017
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Abstract

The composite nanoparticles of un-doped, Fe-doped TiO2, Fe-N co-doped TiO2 were prepared by sol-gel method, and characterized by X-ray diffractomer, scanning electron microscope, and UV-Vis diffuse spectrometer. 2-methylisoborneol (2-MIB) was used as the model compound to investigate the photocatalytic activities of TiO2, and the effect of water quality on 2-MIB removal was also discussed. The results show that the prepared TiO2 was mainly anatase, and the band gap of TiO2 was narrowed and the absorption band moved to the visible direction after Fe3+-N3- doping. The best photocatalytic activity was achieved when 0.001% Fe-0.5% N co-doped TiO2 calcined at 500°C was employed, corresponding to the 2-MIB removal efficiency of 99.90% and pseudo-first order rate constant of 1.371 18 h-1 by photocatalytic oxidation process in 5h.

Published in Science Discovery (Volume 5, Issue 6)
DOI 10.11648/j.sd.20170506.23
Page(s) 469-475
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

TiO2, Fe-N Co-doping, Visible Photocatalysis, 2-MIB

References
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  • APA Style

    Liu Dan, Yuan Rong-fang, Zhou Bei-hai. (2017). Preparation and Characterization of Fe-N Co-doped TiO2 and Its Effect on Photocatalytic Oxidation of 2-MIB in Water. Science Discovery, 5(6), 469-475. https://doi.org/10.11648/j.sd.20170506.23

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    ACS Style

    Liu Dan; Yuan Rong-fang; Zhou Bei-hai. Preparation and Characterization of Fe-N Co-doped TiO2 and Its Effect on Photocatalytic Oxidation of 2-MIB in Water. Sci. Discov. 2017, 5(6), 469-475. doi: 10.11648/j.sd.20170506.23

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    AMA Style

    Liu Dan, Yuan Rong-fang, Zhou Bei-hai. Preparation and Characterization of Fe-N Co-doped TiO2 and Its Effect on Photocatalytic Oxidation of 2-MIB in Water. Sci Discov. 2017;5(6):469-475. doi: 10.11648/j.sd.20170506.23

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  • @article{10.11648/j.sd.20170506.23,
      author = {Liu Dan and Yuan Rong-fang and Zhou Bei-hai},
      title = {Preparation and Characterization of Fe-N Co-doped TiO2 and Its Effect on Photocatalytic Oxidation of 2-MIB in Water},
      journal = {Science Discovery},
      volume = {5},
      number = {6},
      pages = {469-475},
      doi = {10.11648/j.sd.20170506.23},
      url = {https://doi.org/10.11648/j.sd.20170506.23},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20170506.23},
      abstract = {The composite nanoparticles of un-doped, Fe-doped TiO2, Fe-N co-doped TiO2 were prepared by sol-gel method, and characterized by X-ray diffractomer, scanning electron microscope, and UV-Vis diffuse spectrometer. 2-methylisoborneol (2-MIB) was used as the model compound to investigate the photocatalytic activities of TiO2, and the effect of water quality on 2-MIB removal was also discussed. The results show that the prepared TiO2 was mainly anatase, and the band gap of TiO2 was narrowed and the absorption band moved to the visible direction after Fe3+-N3- doping. The best photocatalytic activity was achieved when 0.001% Fe-0.5% N co-doped TiO2 calcined at 500°C was employed, corresponding to the 2-MIB removal efficiency of 99.90% and pseudo-first order rate constant of 1.371 18 h-1 by photocatalytic oxidation process in 5h.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Preparation and Characterization of Fe-N Co-doped TiO2 and Its Effect on Photocatalytic Oxidation of 2-MIB in Water
    AU  - Liu Dan
    AU  - Yuan Rong-fang
    AU  - Zhou Bei-hai
    Y1  - 2017/11/21
    PY  - 2017
    N1  - https://doi.org/10.11648/j.sd.20170506.23
    DO  - 10.11648/j.sd.20170506.23
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 469
    EP  - 475
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20170506.23
    AB  - The composite nanoparticles of un-doped, Fe-doped TiO2, Fe-N co-doped TiO2 were prepared by sol-gel method, and characterized by X-ray diffractomer, scanning electron microscope, and UV-Vis diffuse spectrometer. 2-methylisoborneol (2-MIB) was used as the model compound to investigate the photocatalytic activities of TiO2, and the effect of water quality on 2-MIB removal was also discussed. The results show that the prepared TiO2 was mainly anatase, and the band gap of TiO2 was narrowed and the absorption band moved to the visible direction after Fe3+-N3- doping. The best photocatalytic activity was achieved when 0.001% Fe-0.5% N co-doped TiO2 calcined at 500°C was employed, corresponding to the 2-MIB removal efficiency of 99.90% and pseudo-first order rate constant of 1.371 18 h-1 by photocatalytic oxidation process in 5h.
    VL  - 5
    IS  - 6
    ER  - 

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Author Information
  • Department of Environmental Engineering, University of Science and Technology, Beijing, China

  • Department of Environmental Engineering, University of Science and Technology, Beijing, China

  • Department of Environmental Engineering, University of Science and Technology, Beijing, China

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